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  <title><![CDATA[MS Defense by Ramón Alfonso Sosa]]></title>
  <body><![CDATA[<p><span><span><span><strong><span>THE SCHOOL OF MATERIALS SCIENCE AND ENGINEERING<br />
GEORGIA INSTITUTE OF TECHNOLOGY</span></strong><br />
<span>Under the provisions of the regulations for the degree<br />
MASTER OF SCIENCE<br />
<strong>on Friday, May 12th, 2023</strong></span></span></span></span></p>

<p><span><span><span><strong><span>12:00 PM EST</span></strong><br />
<span>via</span></span></span></span></p>

<p><span><span><span><span>Teams</span></span></span></span></p>

<p>&nbsp;</p>

<p><span><span><span><span><a href="https://teams.microsoft.com/l/meetup-join/19%3ameeting_MzM2YWU3ZmUtOGI5Zi00NDk0LTliNjEtODlkMDQ1N2QyMTZm%40thread.v2/0?context=%7b%22Tid%22%3a%22482198bb-ae7b-4b25-8b7a-6d7f32faa083%22%2c%22Oid%22%3a%2228686a29-7af6-4de4-b491-c7de35808ecd%22%7d">https://teams.microsoft.com/l/meetup-join/19%3ameeting_MzM2YWU3ZmUtOGI5Zi00NDk0LTliNjEtODlkMDQ1N2QyMTZm%40thread.v2/0?context=%7b%22Tid%22%3a%22482198bb-ae7b-4b25-8b7a-6d7f32faa083%22%2c%22Oid%22%3a%2228686a29-7af6-4de4-b491-c7de35808ecd%22%7d</a></span></span></span></span></p>

<p><span><span><span><span>Meeting ID: 288 847 186 38</span></span></span></span></p>

<p><span><span><span><span>Passcode: tATXiZ</span></span></span></span></p>

<p><span><span><span>&nbsp;</span></span></span></p>

<p><span><span><span><span>will be held the</span></span></span></span></p>

<p><span><span><span><span>MASTER’S THESIS DEFENSE<br />
for<br />
Ramón Alfonso Sosa<br />
&nbsp;<br />
“<strong>A MAP TO RELIABLE CHIP-TO-PACKAGE CU-PILLAR INTERCONNECTIONS WITH SINTERED NANOPOROUS-CU CAPS</strong>”</span></span></span></span></p>

<p><br />
<span><span><span><span>&nbsp;<br />
&nbsp; Committee Members:</span></span></span></span></p>

<p><span><span><span><span>Dr. Vanessa Smet, ME (Co-Advisor)<br />
Dr. Antonia Antoniou, ME (Co-Advisor)</span></span></span></span></p>

<p><span><span><span><span>Dr. Rao Tummala, ECE (Co-Advisor)<br />
Dr. Preet Singh, MSE</span><br />
&nbsp;</span></span></span></p>

<p><span><span><span>&nbsp;</span></span></span></p>

<p><span><span><span>&nbsp;</span></span></span></p>

<p><span><span><span><strong><span>Abstract</span></strong><span>: With a continuous drive towards increased performance and miniaturization pushing the frontiers of system-level integration, emerging high-performance computing systems will require chip-to-substrate interconnection solutions that can reliably operate at higher operating temperatures (&gt;100</span><span><span>℃</span></span><span>), current densities (&gt;106 A/cm2), and at finer pitches (&lt;20 µm) expected in these architectures, well beyond the fundamental limits of traditional solder-based interconnections. All-Cu interconnections, the natural next off-chip interconnection node, have been successfully implemented at the foundry level via the now mature hybrid bonding process, though its reliance on expensive chemical-mechanical planarization (CMP) processes and material incompatibilities preclude it from being used at the package level, where the levels of non-coplanarity and warpage that exist cannot be addressed in this manner. Thus, there exists a need for an all-Cu interconnection technology with enhanced tolerance to non-coplanarities that can be used at the chip-to-substrate level.</span></span></span></span></p>

<p><span><span><span><span>Sintered Nanoporous-Cu interconnections are proposed in this research to address this grand challenge. Nanoporous-Cu (NP-Cu) is a spongelike material with an elastic modulus an order of magnitude lower than that of bulk-Cu, giving it enhanced compliance during assembly and allowing it to readily deform under modest pressures to accommodate package-level non-coplanarities. Additionally, the nanoscale structure of NP-Cu allows it to sinter at low temperatures, and is not reliant on organic stabilizers, unlike nanoscale particle systems, minimizing the risk of voiding due to volatiles. </span></span></span></span></p>

<p><span><span><span><span>This thesis presents two parallel thrusts in demonstrating the applicability of nanoporous-Cu as a suitable bonding interface material for chip-to-substrate all-Cu interconnections. The first is a demonstration of the manufacturability of nanoporous-Cu, which can be fabricated through an in-house designed electrodeposition process at fine-pitch of a Cu-Zn precursor alloy and subsequent chemical dealloying of this precursor. An extensive characterization of the wafer-scale Cu-Zn bumping process is presented, including the global, local, and within bump variations in composition of the electrodeposited Cu-Zn precursor, and a study that characterizes the incidence of nodule-type defects on these Cu-Zn bumps. </span></span></span></span></p>

<p><span><span><span><span>The second thrust is an exploration of the bonding parameter space for the formation of robust sintered NP-Cu interconnections. Through this study, the conventional thermocompression bonding process, which relies on extensive time under pressure, commonly used for direct Cu-Cu bonding is replaced by a hot-placement and pressureless sintering approach, which yields low-resistance, high-strength sintered NP-Cu interconnections at modest temperatures and lower placement pressures compared to bulk-Cu bonding. Finally, an evaluation of the reliability of these sintered NP-Cu interconnections under thermal aging, electromigration testing, and thermal cycling testing is presented. </span></span></span></span></p>

<p><span><span><span><span>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; In summary, this work provides a pathway for reliable, fine-pitch all-Cu interconnections at the package level with enhanced tolerance to non-coplanarities using sintered nanoporous-Cu as a bonding interface material.</span></span></span></span></p>

<p>&nbsp;</p>
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